PhD supervisory team
Prof Pola Goldberg Oppenheimer, (GoldberP@bham.ac.uk), School of Chemical Engineering, University of Birmingham
Dr Linh Tran, (linh@milvusadvanced.co.uk), Milvus Advanced
Dr Assia Kasdi, (assia@milvusadvanced.co.uk), Milvus Advanced
Industrial partner
This project is co-funded by Milvus Advanced.
Application deadline
31 March 2024 (23:59)
Start date of the project
Variable
Duration of the PhD
4 years
Funding
Due to some funding and immigration restrictions, the studentship is open to UK students only. Home applicants are eligible for both the cost of tuition fee and a yearly stipend (at UKRI rate) over the course of the PhD programme.
Project summary
Electrolytic hydrogen plays a key-role in decarbonisation and sustainability. However, poor catalytic performance and the use of precious metals as electrocatalysts vastly hinder the industrial implementation. Topological materials having specific surface modification and interesting electronic properties can contribute a new class of superior catalysts for oxygen and hydrogen evolution reactions.[1,2]
This project will explore novel materials possessing high intrinsic activity and durability using virtual high-throughput screening. Material syntheses and characterisations will be carried out not only to verify credibility of the prior computational modelling but also to shed light in mechanistic studies of this type of materials. It will combine topologically intelligent (bi)metallic materials for water splitting with ultrathin topological insulators as shield and allow mass and charge transfer to eliminate metal leaching and increase durability.
Aims and objectives and methodology
(1) Establishing advanced computational modelling and analysis of topological materials for water electrolysis.
(2) Coherent empirical data sets as prior input for statistic calculations and follow-up data to validate the success of the models.
(3) Highly efficient HER/OER electrocatalysts achieved based on computational prediction.
Potential semimetals / Weyl metal/bimetallic compounds will be primarily selected using virtual high-throughput screening. Diverse synthesis methods such as chemical vapour transport, chemical vapour deposition and impregnation will be applied to fabricate materials with different crystalline nanostructures and various nanosizes. Electrochemical evaluation will be conducted to examine catalytic performance of the materials. Material characterizations of pristine samples and post-mortem analysis are the next essential steps to elucidate physical properties and to build the bridge between crystal/electronic structure and electrochemical activities. These experimental data will be used to establish statistical diagnostic models presenting the correlations between topological materials and targeted electrocatalytic properties. Subsequently, once the models are established, novel catalysts will be fabricated, physically analysed and electrochemically tested to satisfy the evaluation circle.
[1]. ACS Appl. Mater. Interfaces 2022, 14, 19324.
[2]. ACS Catal. 2020, 10, 4, 2656.
General eligibility requirements
- An undergraduate degree in Physics, Material Science, Chemistry, Electrical Engineering, Mechanical Engineering or other related disciplines, with at least 2(i) honours or equivalent.
- An interest in interdisciplinary sciences and engineering, with an enthusiasm for communication.
- Evidenced mathematical ability.
- No prior knowledge of topology or topological physics is required.
How to apply
Informal enquires or for more information regarding the project can be addressed to the project supervisor, Prof Pola Goldberg Oppenheimer at GoldberP@bham.ac.uk
To be considered for this studentship, please download the CDT application form (Word), complete and submit to us at cdt-topologicaldesign@contacts.bham.ac.uk. Please read the instruction notes included in the form carefully and make sure that you include a copy of your university transcript and your up-to-date CV in your email.